Step 1: Download Litecoin Core 0.21.2. It will take around 10 hours to install. https://litecoin.org/
Step 2: Once downloaded run Litecoin Core
Step 3: Generate a native segwit (Bech32) address and send a little litecoin to it from another wallet
Step 4: Once the litecoin is received then Generate a MWEB address
Step 5: then copy the ltcmweb1 address
Step 6: go to Send and paste the address (dont send me any LTC to this address, that wallet has been destroyed)
Step 7: Send the litecoin
Step 8: Check your Transactions
Step 9: That's it!
Step 10: For more advanced options such as the ability to select with coins you want to send go to Settings and check Enable coin control features.